|
|
p-coumaric_acid + CoA + ATP <=> 4-coumaroyl-CoA + AMP + diphosphate
|
6.2.1.12
4-coumarate---CoA ligase
6.2.1.2
medium-chain acyl-CoA ligase
6.2.1.30
phenylacetate---CoA ligase
|
–
–
–
|
| |
BRENDA:
BR63
KEGG:
R01616
MetaCyc:
4-COUMARATE--COA-LIGASE-RXN
SABIO-RK:
1761
|
|
|
|
L-tyrosine + 2-oxoglutarate <=> 4-hydroxyphenylpyruvate + L-glutamate
|
2.6.1.1
aspartate transaminase
2.6.1.2
alanine transaminase
2.6.1.24
diiodotyrosine transaminase
2.6.1.27
tryptophan transaminase
2.6.1.39
2-aminoadipate transaminase
2.6.1.42
branched-chain-amino-acid transaminase
2.6.1.49
dihydroxyphenylalanine transaminase
2.6.1.5
tyrosine transaminase
2.6.1.57
aromatic-amino-acid transaminase
2.6.1.7
kynurenine---oxoglutarate transaminase
2.6.1.79
glutamate---prephenate aminotransferase
2.6.1.9
histidinol-phosphate transaminase
|
–
–
–
–
–
–
–
–
–
–
–
–
|
| |
BRENDA:
BR47696
KEGG:
R00734
MetaCyc:
TYROSINE-AMINOTRANSFERASE-RXN
SABIO-RK:
1097
|
|
|
|
(R)-3-(4-hydroxyphenyl)lactate + NADP+ <=> 4-hydroxyphenylpyruvate + NADPH + H+
|
1.1.1.110
aromatic 2-oxoacid reductase
1.1.1.237
hydroxyphenylpyruvate reductase
|
–
–
|
| |
BRENDA:
BR29263;
BS370805
KEGG:
R03339
MetaCyc:
1.1.1.222-RXN
|
|
|
|
4-coumaroyl-4''-hydroxyphenyllactate + reduced_[NADPH-hemoprotein_reductase] + O2 <=> caffeoyl-4''-hydroxyphenyllactate + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14
|
–
|
| |
MetaCyc:
RXN-7628
|
|
|
|
Cinnamic_acid + O2 + reduced_[NADPH-hemoprotein_reductase] <=> p-coumaric_acid + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.14.91
trans-cinnamate 4-monooxygenase
|
–
|
| |
MetaCyc:
TRANS-CINNAMATE-4-MONOOXYGENASE-RXN
|
|
|
|
4-coumaroyl-3,4''-dihydroxyphenyllactate + reduced_[NADPH-hemoprotein_reductase] + O2 <=> rosmarinic_acid + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14
|
–
|
| |
MetaCyc:
RXN-7631
|
|
|
|
4-coumaroyl-4''-hydroxyphenyllactate + reduced_[NADPH-hemoprotein_reductase] + O2 <=> 4-coumaroyl-3,4''-dihydroxyphenyllactate + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14
|
–
|
| |
MetaCyc:
RXN-7630
|
|
|
|
(R)-3-(4-hydroxyphenyl)lactate + 4-coumaroyl-CoA <=> 4-coumaroyl-4''-hydroxyphenyllactate + CoA
|
2.3.1
2.3.1.140
rosmarinate synthase
|
–
–
|
| |
BRENDA:
BS320508
MetaCyc:
RXN-7626
|
|
|
|
caffeoyl-4''-hydroxyphenyllactate + reduced_[NADPH-hemoprotein_reductase] + O2 <=> rosmarinic_acid + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14
|
–
|
| |
MetaCyc:
RXN-7629
|
|
|
|
L-phenylalanine <=> Cinnamic_acid + NH3
|
4.3.1.1
aspartate ammonia-lyase
4.3.1.23
tyrosine ammonia-lyase
4.3.1.24
phenylalanine ammonia-lyase
4.3.1.25
phenylalanine/tyrosine ammonia-lyase
4.3.1.31
L-tryptophan ammonia lyase
4.3.1.5
phenylalanine ammonia-lyase
|
–
–
–
–
–
–
|
| |
BRENDA:
BR3427;
BS445625
KEGG:
R00697
MetaCyc:
PHENYLALANINE-AMMONIA-LYASE-RXN
SABIO-RK:
1076
|
|
